Configurational Behavior and Conductance of Alkanedithiol Molecular Wires from Accelerated Dynamics Simulations

An accelerated dynamics scheme is employed to sample the configurational space of a system consisting of an
alkanedithiol molecule confined to the gap between a metal tip and a perfect metal surface. With this information and by means
of nonequilibrium green functions techniques (NEGF), conductance calculations are performed. The present results show that
even for this system, which is one of the most simple conceivable because of the perfectness of the surface, a complex behavior
appears due to the occurrence of an unexpected tip-molecule-surface arrangement, where the insertion of one of the molecular
ends into the tip−surface gap generates configurations with strongly enhanced conductance. Estimates are also made for the time
required to generate the molecular junction, indicating that it should depend on the tip−surface distance, thus opening the way
to new experiments in this direction.