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Nonmechanical Conductance Switching in a Molecular Tunnel Junction

Author(s):

Adva Baratz, Roi Baer

Journal:

The Journal of Physical Chemistry Letters

Year:

2012

Volume:

3

Pages

498-502

DOI:

10.1021/jz201562a

Abstract:

We present a molecular junction composed of a donor (polyacetylene strands) and an acceptor (malononitrile) connected together via a benzene ring and coupled weakly to source and drain electrodes on each side, for which a gate electrode induces intramolecular charge transfer, switching reversibly the character of conductance. Using a new brand of density functional theory, for which orbital energies are similar to the quasiparticle energies, we show that the junction displays a single, gate-tunable differential conductance channel in a wide energy range. The gate field must align parallel to the displacement vector between donors and acceptor to affect their potential difference; for strong enough fields, spontaneous intramolecular electron transfer occurs. This event radically affects conductance, reversing the charge of carriers, enabling a spin-polarized current channel. We discuss the physical principles controlling the operation of the junction and find interplay of quantum interference, charging, Coulomb blockade, and electron–hole binding energy effects. We expect that this switching behavior is a generic property for similar donor–acceptor systems of sufficient stability.

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