top of page
< Back

Characteristics of Amine-Ended and Thiol-Ended Alkane Single-Molecule Junctions Revealed by Inelastic Electron Tunneling Spectroscopy

Author(s):

Youngsan Kim, Thomas Julian Hellmuth, Marius Bürkle, Fabian Pauly, Elke Scheer

Journal:

ACS Nano

Year:

2011

Volume:

5

Pages

4104-4111

DOI:

10.1021/nn200759s

Abstract:

A combined experimental and theoretical analysis of the charge transport through single-molecule junctions is performed to define the influence of molecular end groups for increasing electrode separation. For both amine-ended and thiol-ended octanes contacted to gold electrodes, we study signatures of chain formation by analyzing kinks in conductance traces, the junction length, and inelastic electron tunneling spectroscopy. The results show that for amine-ended molecular junctions no atomic chains are pulled under stretching, whereas the Au electrodes strongly deform for thiol-ended molecular junctions. This advanced approach hence provides unambiguous evidence that the amine anchors bind only weakly to Au.

© Molecular Junction Database | University of Southern California. All rights reserved.

bottom of page