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Single-Molecule Junctions Based on Nitrile-Terminated Biphenyls: A Promising New Anchoring Group

Author(s):

Artem Mishchenko, Linda A. Zotti, David Vonlanthen, Marius Bürkle, Fabian Pauly, Juan Carlos Cuevas, Marcel Mayor, Thomas Wandlowski

Journal:

Journal of the American Chemical Society

Year:

2011

Volume:

133

Pages

184-187

DOI:

10.1021/ja107340t

Abstract:

We present a combined experimental and theoretical study of the electronic transport through single-molecule junctions based on nitrile-terminated biphenyl derivatives. Using a scanning tunneling microscope-based break-junction technique, we show that the nitrile-terminated compounds give rise to well-defined peaks in the conductance histograms resulting from the high selectivity of the N−Au binding. Ab initio calculations have revealed that the transport takes place through the tail of the LUMO. Furthermore, we have found both theoretically and experimentally that the conductance of the molecular junctions is roughly proportional to the square of the cosine of the torsion angle between the two benzene rings of the biphenyl core, which demonstrates the robustness of this structure−conductance relationship.

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